Biomase
 
 

Cea mai folosită metodă īn prezent

Am amestecat aici şi alternativele biologice de producere a combustibililor cāt şi tratarea deşeurilor

Situaţia actuală

 Avionul cu soia. De ce zāmbiţi? Nu e deloc ridicol. Vă rog să nu rādeţi. E absolut normal. American Chemical Society in Anaheim, California, susţine că amestecul de soia īn kerosen este solutia crizei petroliere.
Dar au uitat sa calculeze cāte hectare de soia vă trebuiesc pentru un zbor, să zicem de la Bucureşti păna la Braşov. Şi asta ar fi doar una din probleme. http://www.eurekalert.org/pub_releases/2004-03/ns-sp032404.php
Una din problemele majore este faptul că flota actuală de avioane (11.000) , nu poate fi făcută să zboare cu altceva īn loc de kerosen. Airbus au studiat cāteva variante cu hidrogen dar nu au ajuns nicăieri.

Ok, poate nu cu soia, dar de spanac ce ziceţi? Spinach Could Power Better Solar Cells.

 
Metan există īn cantităţi enorme īn apa mări. Există microbi care produc metan. Chiar īn Marea Neagră. Problema e cum īl extragi?
 

Depolimerizarea termală nu intra īn calcul ca energie alternativă. Acest proces transforma gunoiul cu baza organica īnapoi īn combustibili din hidrocarburi. Este foarte folositor şi va atenua mult din şocul energetic, dar nu va īnlocui combustibili fosili. De ce? Pentru că gunoiul a fost produs iniţial din şi cu ajutorul combustibililor fosili. Acest proces nu va avea niciodata rata energetică pozitivă a combustibilului original. Pe masură ce sursa scade (petrolul, gazul natural) şi materialul de bază necesar acestui proces se va diminua. Thermal Depolymerization (TD) is a process being developed by Changing World Technology. The process turns waste into oil.  It is often touted as a "solution" to the oil crisis
 
False Hope- Why Thermal Depolymerization
The biggest problem with TD is that it is being advertised as a means to maintain business as usual. Such advertising promotes further consumption, provides us with a dangerously false sense of security, and encourages us to continue thinking that we don't need to make this issue a priority.

Despre Biocombustibil:

Schematically, there are two types of cultures that allow to obtain a liquid fuel from a field (which is the usual way to obtain a biofuel !) :

 plants that produce "oily" seeds, such as sunflowers or colza ; the oil obtained can be used as diesel oil,

 plants that produce starch or sugar, that will then give alcohol after fermentation. Here we will mostly find sugar cane and beets, but sometimes wheat is also used.

On the grounds of gross outputs, we can make a first rough calculation of the surface that it is necessary to allocate to "energetic crops" to replace by biofuels produced in France all oil used for transportation in France, that is 50 millions tonnes (or 50 Mtoe) :

 

 
Line
 
Type of crop
 
Weight of fuel per hectare
 
Tonnes oil equivalent per tonne of oil
 
Gross enery yielded by hectare (tonnes oil equivalent)
 
Minimum number of km2 required to produce 50 Mtoe
 
In % of the french territory
 
In % of cultivated land (in 1997)
Oil Colza  
1,37
 
1
 
1,37
 
365.000
 
66%
 
232%
Oil Sunflower  
1,06
 
1
 
1,06
 
472.000
 
86%
 
300%
Ethanol Sugar beet  
5,78
 
0,69
 
3,98
 
125.500
 
23%
 
80%
Ethanol Wheat  
2,55
 
0,69
 
1,76
 
284.000
 
52%
 
183%
source : report DIDEM/ADEME on biofuels, 2003
 

The above percentages, obtained on the grounds of gross outputs, are already significant : we understand right away that we (in France) will never substitue all gasoline by "oily biofuels". Nevertheless, it remains possible, when looking at there figures, to think that we have a real potential with beets. Alas, things are not so simple, and we must reason with the NET output of this line. Indeed, to obtain these biofuels, it is necessary to spend some energy :

 it is necessary to put some fuel in the tractor,

 it is necessary to manufacture fertilizers (it is the first source of energy spending for this step, because agro chemistry is very energy intensive),

 it is necessary to crush and purify the product of the culture,

 and most of it, to obtain alcohol, it is necessary to distil the "juice" after fermentation.

If we want to totally replace oil (and natural gas, that is no more renewable) by biofuels, it is not by using oil (and gas, for fertilizers) to produce these biofuels that we will manage to do so ! Therefore we must deduct from the gross energy obtained the upstream consumptions, for fertilizer manufacturing, culture, cropping, and processing after crop.

Well taking into account all these upstream consumptions will lead to net outputs much inferior, and almost null for ethanol ex-wheat.

 

 
Line
 
Type of crop
 
Gross energy yielded by hectare (tonnes oil equivalent)
 
Energy required for fertilizer manufacturing, tractor powering and distillation (tonnes oil equivalent per hectare)
 
Net energy yielded by hectare (tonnes oil equivalent)
 
Minimum number of km2 required to produce 50 Mtoe
 
In % of the French territory
 
In % of cultivated land (in 1997)
Oil Colza  
1,37
 
0,50
 
0,87
 
574.000
 
104%
 
365%
Oil Sunflower  
1,06
 
0,29
 
0,77
 
648.000
 
118%
 
413%
Ethanol Sugar beet  
3,98
 
3,22
 
0,76
 
660.000
 
120%
 
420%
Ethanol Wheat  
1,76
 
1,72
 
0,04
 
14.800.000 !
 
2700%
 
9400% !

 

Why such a drop for beets ? It is that distillation consumes a lot of energy, about the 2/3rds of the energy "enclosed" in the alcohol obtained. The energy required for fertilizer manufacturing and powering the tractor do the rest. Thus "all crops are equal" and yield a net output of 0,75 tonne oil equivalent per hectare, except wheat that yields almost nothing on a net basis.

To produce 50 millions tonnes oil equivalent, we should thus mobilize, in rough figures, 3 to 4 times the present arable land surface of our country. Of course this is not possible, and even producing 10% of this amount out of biofuels would require 30 to 40% of the present cultivated land, and we did not mention oil for heating so far.

One can therefore easily realize that biofuels will not allow to substitute "one day" the oil that we presently consume, and not even a significant fraction of it. In other words, to consider that it is not annoying to have a way of life heavily dependant on fossil fuels because, "one day", we will all be able to drive (and heat ourselves) on biofuels is alas to cherish an illusion. http://www.manicore.com/anglais/documentation_a/carb_agri_a.html

Dr. Walter Younquist points out:
Ethanol production survives only by the grace of a subsidy by the US government from taxpayer dollars. Continuing the production of ethanol is purely a device for buying the Midwest US farm vote.
[Not surprisingly] the fact that the company which makes 60% of US ethanol is also one of the largest contributors of campaign money to the Congress – a distressing example of politics overriding logic.


Biomass Fuels.  These fuels derive from wood, corn, sugarcane (the most hopeful candidate for producing the liquid fuel ethanol); and also, substantially, from crop residues and dung, although using these has a “devastating effect on the productivity of agricultural soils” (P&P:151).  The ultimate limit to energy yield is the ability of plants to capture the sun’s power.  In the temperate zone, estimates are that 0.07% of sunlight is fixed in terrestrial ecosystems, and that in agricultural systems this rises to about 0.1% (P&P:14).  Average annual North American insolation amounts to 1900 kW/ha, thus a practical limit to capturing energy is about 0.001 x 1900 = 1.9 kW of thermal energy per ha.  It is not easy to envisage the effect of needing 1.9 hectares to gather a kilowatt of thermal energy.  Perhaps it helps to note that were Britain to be thus restricted, then in order to replace the 5.2 kW/cap presently obtained from fossil fuels, and to be self-supporting, Britain would have to reduce its present population of 58 million to a mere 6 million.  A similar calculation for the USA indicates a need to reduce population from about 265 million to 55 million.

It might be thought that the heavy yields available from sugarcane would allow far better energy capture than 1.9 kW/ha.  We have written a separate working paper on this, Sugarcane and Energy, since some of the “supplementary data” in Pimentel and Pimentel, 1996 pp. 236-239, relating to sugarcane are incorrect.  We got correct data from the Mauritius Sugar Industry Research Institute.  The calorific value of sugarcane is about 1212 kcal/kg.  After allowing for inputs, the net output as raw sugarcane is 10.5 kW/ha.  However this is an unrealistic assessment, because it fails to take into account that a considerable part of the inputs needed are higher grade fuels, such as ethanol.  Thus the more realistic question is this: what is the energy value of the ethanol yield that can be obtained from 1 ha of sugarcane, that will be available for use (rather than needed as input)?  For the U.S., assuming the average sugarcane yield of 74 tonnes/ha, the answer is 2.1 kWyr/ha/yr.  In other words a steady supply of 2.1 kW/ha.

Incidentally, the 0.1 percent datum mentioned earlier, for temperate zone plant-energy-capture, receives confirmation from the forestry data used by Wackernagel et al (1997) in their spreadsheets. 
 

The truth is ethanol is no replacement for oil. It's not even a viable supplement.

It takes 11 acres to grow enough corn to fuel one automobile with ethanol for 10,000 miles, or about a year’s driving. If we tried to replace just 10 percent of the gasoline the U.S. will use in 2020 with corn-based ethanol, we would need to plant an area equivalent to Illinois, Indiana and Ohio solely to grow the grain needed as feedstock. The difficulty of that can be appreciated when you realize that this area is about one-sixth of the land we currently use in the United States for growing all our crops
 


       The U. K. carrying capacity estimate of 6 million, based on biomass, derives from the estimated 1.9 kW/ha and the March 1997 data of Wackernagel et al as follows.  To replace the current U. K. fossil fuel use of 5.19 kW/cap at a rate of 1.9 kW/ha requires 5.19 / 1.9 = 2.73 ha/cap.  United Kingdom citizens are estimated to currently use 0.11 ha/cap of arable land,  0.27 ha/cap of pasture, and 0.10 ha/cap to provide forest products (all these are U. K. areas, not worldwide productivity areas).  This gives a total of 3.21 ha/cap.  Dividing this into Britain’s 20 million hectares of ecologically productive land gives a carrying capacity of 6 million people.  In the calculation for the United States, the sustainability buffers used for our normal carrying capacity calculations were retained, as well as the 12% biodiversity buffer; this gave an ecologically productive area of 439 million ha, and a total “footprint” of 7.98 ha/cap, giving a population limit of 55 million.  These calculations are purely to demonstrate the general effect of energy-capture at 1.9 kW/ha.  U. K. forests, and U. S. forests (just possibly), may be nearly three times as productive as world averages.  Forest yield factors are very hard to estimate.

      For the average U.S. sugarcane yield of 74 t/ha, the gross calorific value is 74,000 x 1212 = 89.7 million kcal.  On a pro rata basis, using P&P page 237, the input needed to produce this 74 tons is 10.3 million kcal/ha.  Thus net energy-capture = 79.4 million kcal/ha = 10.5 kW/ha. 

The ethanol calculation for sugarcane is made simple because all the heat needed for conversion is provided by the bagasse, the non-sugar part of the crop.  Thus all additional inputs are higher-grade fuels.  Thus we can take the additional inputs (beside the bagasse) as being taken from the ethanol output.  The amount of the gross ethanol output which is needed to feed the input is about 0.47, leaving 0.53 as net output.  However the biggest attenuation comes in the conversion itself:  13 kg of sugarcane, — to take an intermediate figure — with a calorific value of 13 x 1,212 = 15,756 kcal, produces 1 liter of ethanol, with a calorific value of 5,130 kcal.  Energy attenuation is therefore 5,130 / 15,756 = 0.326.  The aggregate attenuation is therefore 0.53 x 0.326 = 0.173.  Applying this to the gross calorific value of 74 tonnes, amounting to 11.91 kW/ha, gives 2.1 kW/ha.  Note a steady flow of 2.1 kW/ha can also be described, in terms of an amount of energy, as 2.1 kWyr/ha/yr.

   Worldwide forest absorption capacity should be a rough guide to temperate-zone photosynthesis — which presumably lies somewhere between boreal and tropical forest productivity.  In their March 1997 spreadsheets, Wackernagel et al (1997) used a worldwide forest carbon absorption capacity of 1.8 metric tons of carbon per ha.  This datum derived from Yoshihiko Wada’s (1994) survey of the literature.  In the November 1997 revision to the spreadsheets, the data used came from the Intergovernmental Panel on Climate Change, which reduced the absorption capacity datum to 1.42 tC/ha.  Wood has an energy/carbon ratio of about 38.46 GJ/tC = 1.22 kWyr/tC.  Thus the earlier and later datums indicate energy outputs of about: 1.8 x 1.22 = 2.2 kW/ha and 1.42 x 1.22 = 1.7 kW/ha.  These estimates, 2.2 kW/ha and 1.7 kW/ha, bracket the 1.9 kW/ha figure which we derived from the temperate-zone, agricultural, plant-energy-capture datum of 0.001.  

 ftp://members.aol.com/optjournal/comsense.doc
 

 Oil from biomass
Oil from biomass can supplement fossil oil. In Denmark, about 1,000 litres (34 GJ) of
bio-diesel can be produced from the rape grown on one hectare. Thus, to cover Denmark’s
present annual oil consumption for road transport (160 PJ/year) by bio-diesel, crops
suitable for bio-diesel production must be grown on an area of about 47,000 square
kilometres or about 1.6 times Denmark’s cultiv ated area. Hence, oil consumption must be
substantially
reduced if oil from biomass is to cover a major portion of the oil consumption.
Alcohol (ethanol) can be produced from crops such as sugar cane, grain, and elephant
grass. Depending on the crop, the soil and the climate, the yield amounts to 60 - 100 GJ
per hectare, i.e. 2 - 3 times more than the bio-diesel yield. Alcohol can be added to petrol
and thus substitute oil. Also, engines can be designed to run entirely on alcohol.
 

Wood and other biomass. Wood has long been used as a fuel, now to the extent that large areas worldwide are being deforested resulting in massive erosion in such places as the foothills of the Himalayas, and the mountains of Haiti. Wood can be converted to a liquid fuel but the net energy recovery is low, and there is not enough wood available to be able to convert it to a liquid fuel in any significant quantities.

Other biomass fuel sources have been tried. Crops such as corn are converted to alcohol. In the case of corn to ethanol, it is an energy negative. It takes more energy to produce ethanol than is obtained from it (Pimentel, 1998). Also, using grain such as corn for fuel, precludes it from being used as food for humans or livestock. It is also hard on the land. In U.S. corn production, soil erodes some 20-times faster than soil is formed. Ethanol has less energy per volume than does gasoline, so when used as a 10 percent mix with gasoline (called gasohol), more gasohol has to be purchased to make up the difference. Also, ethanol is not so environmentally friendly as advocates would like to believe. Pimentel (1998) states:

Ethanol produces less carbon monoxide than gasoline, but it produces just as much nitrous oxides as gasoline. In addition, ethanol adds aldehydes and alcohol to the atmosphere, all of which are carcinogenic. When all air pollutants associated with the entire ethanol system are measured, ethanol production is found to contribute to major air pollution problems.

With a lower energy density than gasoline, and adding the energy cost of the fertilizer (made chiefly from natural gas), and the energy costs (gasoline and/or diesel) to plow, plant, cultivate, and transport the corn for ethanol production, ethanol in total does not save fossil fuel energy nor does it's use reduce atmospheric pollution.

A comprehensive study of converting biomass to liquid fuels by Giampietro and others (1997) concludes:

Large scale biofuel production is not an alternative to the current use of oil, and is not even an advisable option to cover a significant fraction of it.

 

http://hubbert.mines.edu/news/v98n2/mkh-new7.html

1112.pdf

 http://www.changingworldtech.com/

 http://www.cpast.org/Articles/fetch.adp?topicnum=13

 http://www.uce-uu.nl/showproject.php?id=3

http://forums.biodieselnow.com/topic.asp?TOPIC_ID=829

http://lists.justnet.info/pipermail/asc-media/2003-August/000391.html

http://me.queensu.ca/courses/MECH430/Assets/Files/Recommended%20Reading/Power%20Table%20.pdf

http://igadrhep.energyprojects.net/GetDoc.asp?DocumentID=6

http://www.age.uiuc.edu/bee/RESEARCH/tcc/tccpaper3.htm#four

http://www.csis.org/stratassessment/reports/energyvii81298.pdf 

http://www.methanol.org/methanol/index.cfm